Ethylene Chlorotrifluoroethylene
ECTFE stands for Ethylene Chlorotrifluoroethylene, which can go by the trademark Halar™, is a high-performance fluoropolymer that is known for its exceptional chemical resistance and mechanical properties. It is part of the family of fluoropolymers, which also includes FEP (Fluorinated Ethylene Propylene) and PFA (Perfluoroalkoxy). While all three are fluoropolymers, they have distinct characteristics that set them apart from each other:
- Chemical Resistance: ECTFE offers superior chemical resistance compared to both FEP and PFA. It can withstand a broader range of aggressive chemicals, including strong acids, alkalis, and organic solvents. This makes it an excellent choice for applications where exposure to harsh chemicals is expected.
- Mechanical Strength: ECTFE is mechanically stronger and tougher than FEP and PFA. It has better abrasion resistance and can withstand more physical stress and impact, making it suitable for applications that require robust materials.
- Temperature Range: ECTFE has a broader temperature operating range compared to FEP and PFA. It can typically handle temperatures from approximately -76°C to +150°C (-105°F to +302°F), providing better performance in both high and low-temperature environments.
- Electrical Properties: While FEP and PFA are excellent electrical insulators, ECTFE has slightly lower dielectric strength and is a weaker electrical insulator. This can be a consideration in applications where electrical insulation is a critical requirement.
- Transparency: FEP is known for its exceptional transparency and light transmission, making it suitable for applications where optical clarity is essential. ECTFE is less transparent and may not be as suitable for applications requiring high optical clarity.
- Cost: ECTFE tends to be more expensive than FEP and PFA. The increased cost is primarily due to its superior chemical resistance and mechanical properties.
In summary, ECTFE is a high-performance fluoropolymer with excellent chemical resistance and mechanical strength. It surpasses FEP and PFA in these aspects but may have slightly lower electrical properties and transparency. It is commonly used as a coating where its excellent chemical resistance and abrasion resistance makes it an ideal choice for valves and pumps. In sheet form it is used as a liner for steel and GRP vessels and tanks. Thin film has been used as a release film in carbon fibre composite manufacturing.

When selecting a fluoropolymer for a specific application, Holscot’s expert engineers and customer service team will consider factors such as chemical compatibility, mechanical requirements, temperature range, and cost to determine the most suitable material.
Trade Names for ECTFE resins include Solvay Solexis Halar™
Technical Data for ECTFE:
| Property | Value | Units | Method |
|---|---|---|---|
| Mechanical Properties | |||
| Tensile Strength, 23°C | 6960 48 |
psi MPa |
D 638 |
| Elongation at break, 23°C | 200-300 | % | |
| Impact Strength, Izod, 23°C | No break | J/m | D 256 |
| Yield Strength At 23°C | 4500 | psi | |
| Density | 1.7 | gm/cu.cm | |
| Thermal Properties | |||
| Melting Point | 240 | °C | |
| Service Temperature | 150 | °C | |
| Processing Temperature | 240 | °C | |
| Other Properties | |||
| Tensile Modulus | 240 | ksi | D 638 |
| Specific Gravity | 1.7 | ||
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